000			03391nam a22005175i 4500
001			978-3-319-02660-2
003			DE-He213
005			20140220082511.0
007			cr nn 008mamaa
008			131113s2014 gw | s |||| 0|eng d
020			_a9783319026602 _9978-3-319-02660-2
024	7		_a10.1007/978-3-319-02660-2 _2doi
050		4	_aQC176.8.S8
050		4	_aQC611.6.S9
050		4	_aQC176.84.S93
072		7	_aPHFC _2bicssc
072		7	_aSCI077000 _2bisacsh
082	0	4	_a530.417 _223
100	1		_aKrull, Cornelius. _eauthor.
245	1	0	_aElectronic Structure of Metal Phthalocyanines on Ag(100) _h[electronic resource] / _cby Cornelius Krull.
264		1	_aCham : _bSpringer International Publishing : _bImprint: Springer, _c2014.
300			_aXVII, 146 p. 81 illus., 54 illus. in color. _bonline resource.
336			_atext _btxt _2rdacontent
337			_acomputer _bc _2rdamedia
338			_aonline resource _bcr _2rdacarrier
347			_atext file _bPDF _2rda
490	1		_aSpringer Theses, Recognizing Outstanding Ph.D. Research, _x2190-5053
505	0		_aAbstract -- Introduction -- Molecular electronics -- Experimental techniques -- Introduction to the Kondo effect -- Adsorption of Metal Phthalocyanines on Ag(100) -- Electronic and magnetic properties of MePc on Ag(100) -- Doping of MePc: Alkali and Fe atoms -- Conclusions and Outlook -- Appendix: CuPc on Au(111).
520			_aThe application of molecules in technological devices hinges on the proper understanding of their behavior on metallic electrodes or substrates. The intrinsic molecular electronic and magnetic properties are modified at a metallic interface, and greatly depend on the atomic configuration of the molecule-metal bond. This poses certain problems, such as the lack of reproducibility in the transport properties of molecular junctions, but also offers the possibility to induce new charge and spin configurations that are only present at the interface. The results presented in this thesis address this issue, providing a comprehensive overview of the influence of molecule-metal and molecule-molecule interactions on the electronic and magnetic properties of molecules adsorbed on metallic substrates. Using metal-phthalocyanines (MePc), a commonly used metal-organic complex as a model system, each chapter explores different aspects of the interaction with silver surfaces: the local adsorption geometry, self-assembly, the modifications of the electronic and magnetic characteristics due to hybridization and charge transfer, and finally the manipulation of molecular charge and spin states by electron doping using alkali atoms moved with the STM tip.
650		0	_aPhysics.
650		0	_aChemistry, Organic.
650		0	_aOptical materials.
650	1	4	_aPhysics.
650	2	4	_aSurface and Interface Science, Thin Films.
650	2	4	_aOptical and Electronic Materials.
650	2	4	_aOrganometallic Chemistry.
650	2	4	_aSpectroscopy and Microscopy.
650	2	4	_aAtomic, Molecular, Optical and Plasma Physics.
710	2		_aSpringerLink (Online service)
773	0		_tSpringer eBooks
776	0	8	_iPrinted edition: _z9783319026596
830		0	_aSpringer Theses, Recognizing Outstanding Ph.D. Research, _x2190-5053
856	4	0	_uhttp://dx.doi.org/10.1007/978-3-319-02660-2
912			_aZDB-2-PHA
999			_c92894 _d92894