000 | 03117nam a22004815i 4500 | ||
---|---|---|---|
001 | 978-3-319-01499-9 | ||
003 | DE-He213 | ||
005 | 20140220082508.0 | ||
007 | cr nn 008mamaa | ||
008 | 131101s2014 gw | s |||| 0|eng d | ||
020 |
_a9783319014999 _9978-3-319-01499-9 |
||
024 | 7 |
_a10.1007/978-3-319-01499-9 _2doi |
|
050 | 4 | _aQD505 | |
072 | 7 |
_aPNRD _2bicssc |
|
072 | 7 |
_aSCI013060 _2bisacsh |
|
082 | 0 | 4 |
_a541.395 _223 |
100 | 1 |
_aSchweinberger, Florian Frank. _eauthor. |
|
245 | 1 | 0 |
_aCatalysis with Supported Size-selected Pt Clusters _h[electronic resource] : _bFundamental UHV and Applied Ambient Experiments / _cby Florian Frank Schweinberger. |
264 | 1 |
_aCham : _bSpringer International Publishing : _bImprint: Springer, _c2014. |
|
300 |
_aXXI, 222 p. 136 illus., 91 illus. in color. _bonline resource. |
||
336 |
_atext _btxt _2rdacontent |
||
337 |
_acomputer _bc _2rdamedia |
||
338 |
_aonline resource _bcr _2rdacarrier |
||
347 |
_atext file _bPDF _2rda |
||
490 | 1 |
_aSpringer Theses, Recognizing Outstanding Ph.D. Research, _x2190-5053 |
|
505 | 0 | _aIntroduction -- Background and methods -- Literature survey and theory -- Experimental methods -- Ultra high vacuum -- Model catalysts under vacuum conditions -- Ambient -- Cluster catalysts under applied conditions -- Conclusion and outlook. | |
520 | _aIn his thesis, Florian Schweinberger investigates the influence of the precise size of catalytically active species on reactivity. In order to do this he carries out studies both in UHV and under ambient conditions for supported, size-selected Platium clusters (8-68 atoms). Schweinberger probed the electronic structure, adsorption properties and reactivity of two olefins on surfaces and Pt clusters in the submonolayer range. With adsorbed trichloroethene (TCE) a possible cluster-adsorbate induced change in the electronic structure, and for ethene a low-temperature, size-dependent self-/hydrogenation was observed.In a collaborative approach, Schweinberger and colleagues investigated Pt clusters under ambient pressure conditions. They characterised the clusters at at the local and integral level and tested for temperature stability. Experiments in gas phase ?-reactors and in liquid, as part of a hybrid photocatalytic system, revealed size-dependent reactivity.Overall this thesis is not only of interest for those who want to perform similar experiments but also provides superb scientific insights for researchers in the field. | ||
650 | 0 | _aChemistry. | |
650 | 0 | _aChemistry, Physical organic. | |
650 | 0 | _aCatalysis. | |
650 | 0 | _aRenewable energy sources. | |
650 | 1 | 4 | _aChemistry. |
650 | 2 | 4 | _aCatalysis. |
650 | 2 | 4 | _aPhysical Chemistry. |
650 | 2 | 4 | _aRenewable and Green Energy. |
710 | 2 | _aSpringerLink (Online service) | |
773 | 0 | _tSpringer eBooks | |
776 | 0 | 8 |
_iPrinted edition: _z9783319014982 |
830 | 0 |
_aSpringer Theses, Recognizing Outstanding Ph.D. Research, _x2190-5053 |
|
856 | 4 | 0 | _uhttp://dx.doi.org/10.1007/978-3-319-01499-9 |
912 | _aZDB-2-CMS | ||
999 |
_c92673 _d92673 |