000			03450nam a22004935i 4500
001			978-3-642-14840-8
003			DE-He213
005			20140220084543.0
007			cr nn 008mamaa
008			101110s2010 gw | s |||| 0|eng d
020			_a9783642148408 _9978-3-642-14840-8
024	7		_a10.1007/978-3-642-14840-8 _2doi
050		4	_aQD450-882
072		7	_aPNR _2bicssc
072		7	_aSCI013050 _2bisacsh
082	0	4	_a541 _223
100	1		_aBuchner, Florian. _eauthor.
245	1	0	_aSTM Investigation of Molecular Architectures of Porphyrinoids on a Ag(111) Surface _h[electronic resource] : _bSupramolecular Ordering, Electronic Properties and Reactivity / _cby Florian Buchner.
264		1	_aBerlin, Heidelberg : _bSpringer Berlin Heidelberg, _c2010.
300			_aXXVII, 164 p. _bonline resource.
336			_atext _btxt _2rdacontent
337			_acomputer _bc _2rdamedia
338			_aonline resource _bcr _2rdacarrier
347			_atext file _bPDF _2rda
490	1		_aSpringer Theses
505	0		_aResults -- Self-Assembly and Individual Appearance of Tetraphenylporphyrins on Ag(111) -- Self-Assembly and Individual Appearance of Cobalt(II)-Tetrakisditertbutylphenylporphyrins on Ag(111) -- Coordination of Iron and Cobalt Atoms by Tetraphenylporphyrin Monolayers on Ag(111) and Formation of Metal(II)-Tetraphenylporphyrin -- Different Aspects of 2H-Tetrakis-di-tert-butylphenylporphyrin on Ag(111) -- Direct Metalation of a Phthalocyanine Monolayer on Ag(111) with Co-adsorbed Iron Atoms -- Multicomponent Adlayers of Tetraphenylporphyrins on Ag(111) -- Modification of the Growth of Iron on Ag(111) by Predeposited Organic Monolayers -- Geometric and Electronic Aspects of CoTPP upon Dosage of NO -- Self-Assembly and Voltage-Dependent Appearance of Octaethylporphyrins -- Summary and Outlook -- Fundamentals -- Experimental Setup.
520			_aThe self-assembly of large organic molecules has become a vividly explored and interdisciplinary field in science. One major goal is the tailored fabrication of highly ordered, molecular networks, which are stabilized on a metal surface. Metalloporphyrins receive particular attention, because their distinct intrinsic functionalities make them promising candidates for applications in chemical sensors, solar cells, and for tailored catalytic processes. Based on scanning tunneling microscopy investigations, several novel and fundamental contributions are presented, which has led to a new level of understanding. Highlights are the results with respect to intramolecular conformation and supramolecular ordering, electronic interactions with the substrate, surface confined synthesis such as in-situ metallation reactions, and ligand effects.The number of publications this work has led to emphasises its quality and significance.
650		0	_aChemistry.
650		0	_aAnalytical biochemistry.
650		0	_aChemistry, Physical organic.
650		0	_aElectric engineering.
650	1	4	_aChemistry.
650	2	4	_aPhysical Chemistry.
650	2	4	_aAnalytical Chemistry.
650	2	4	_aSurface and Interface Science, Thin Films.
650	2	4	_aEnergy Technology.
710	2		_aSpringerLink (Online service)
773	0		_tSpringer eBooks
776	0	8	_iPrinted edition: _z9783642148392
830		0	_aSpringer Theses
856	4	0	_uhttp://dx.doi.org/10.1007/978-3-642-14840-8
912			_aZDB-2-CMS
999			_c112543 _d112543