000 02671nam a22004695i 4500
001 978-3-642-20817-1
003 DE-He213
005 20140220083802.0
007 cr nn 008mamaa
008 110810s2011 gw | s |||| 0|eng d
020 _a9783642208171
_9978-3-642-20817-1
024 7 _a10.1007/978-3-642-20817-1
_2doi
050 4 _aQD415-436
072 7 _aPNN
_2bicssc
072 7 _aSCI013040
_2bisacsh
082 0 4 _a547
_223
100 1 _aSundaram, S.
_eauthor.
245 1 0 _aChromium -VI Reagents: Synthetic Applications
_h[electronic resource] /
_cby S. Sundaram, P.S. Raghavan.
264 1 _aBerlin, Heidelberg :
_bSpringer Berlin Heidelberg,
_c2011.
300 _aXII, 66p. 59 illus.
_bonline resource.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
347 _atext file
_bPDF
_2rda
490 1 _aSpringerBriefs in Molecular Science,
_x2191-5407
505 0 _aIntroduction -- Reagent classification -- Synthetic strategies -- Kinetic aspects -- Solid supported Cr(VI) reagents -- Chromium in Biology.
520 _aChromic acid and chromium oxide are the two versatile Cr(VI) oxidants known to organic chemists for decades. The introduction of the Core's reagent , viz: pyridinium chlorochromate, in 1975 followed by the publications on several Cr(VI) oxidizing agents containing the -onium chromates and halochromates in the last three decades have very much changed the chemistry of oxidations with Chromium VI. Several of these new reagents have been shown to be mild so that they can be handled easily and the reacton products may also be controlled. Some of them are highly selective oxidants for positions like allylic hydroxylic group, etc., and some other are highly regioselective. The information on more than 36 such reagents reported in various internationally reputed journals spanning about 280 references have been collected and provided in this book in such a manner that it will be very useful for professionals, researchers, teachers and graduate students working in organic synthesis.
650 0 _aChemistry.
650 0 _aChemistry, Organic.
650 0 _aBiochemistry.
650 1 4 _aChemistry.
650 2 4 _aOrganic Chemistry.
650 2 4 _aBiochemistry, general.
700 1 _aRaghavan, P.S.
_eauthor.
710 2 _aSpringerLink (Online service)
773 0 _tSpringer eBooks
776 0 8 _iPrinted edition:
_z9783642208164
830 0 _aSpringerBriefs in Molecular Science,
_x2191-5407
856 4 0 _uhttp://dx.doi.org/10.1007/978-3-642-20817-1
912 _aZDB-2-CMS
999 _c107848
_d107848