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008 120914s2012 ne | s |||| 0|eng d
020 _a9789048136988
_9978-90-481-3698-8
024 7 _a10.1007/978-90-481-3698-8
_2doi
050 4 _aQD415-436
072 7 _aPNN
_2bicssc
072 7 _aSCI013040
_2bisacsh
082 0 4 _a547
_223
100 1 _aPérez, Pedro J.
_eeditor.
245 1 0 _aAlkane C-H Activation by Single-Site Metal Catalysis
_h[electronic resource] /
_cedited by Pedro J. Pérez.
264 1 _aDordrecht :
_bSpringer Netherlands :
_bImprint: Springer,
_c2012.
300 _aXIV, 269 p. 272 illus.
_bonline resource.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
347 _atext file
_bPDF
_2rda
490 1 _aCatalysis by Metal Complexes,
_x0920-4652 ;
_v38
505 0 _aForeword by Robert G. Bergman -- Introduction: Alkane C—H Activation by Single-Site Metal Catalysis -- Alkane Functionalization via Electrophilic Activation -- Catalytic Carbon–Boron Bond Formation via Activation of Alkane C–H Bonds -- Alkane Dehydrogenation -- Alkane C-H Oxygenation Catalyzed by Transition Metal Complexes -- Alkane Catalytic Functionalization by Carbene or Nitrene Insertion Reactions.
520 _aOver the past decade, much research effort has been devoted to the design and synthesis of new reagents and catalysts that can influence carbon-hydrogen bond activation, mainly because of the prospect that C−H activation could enable the conversion of cheap and abundant alkanes into valuable functionalized organic compounds. Alkane C-H Activation by Single-Site Metal Catalysis presents the current state-of-the-art development in the catalytic systems for the catalytic trans-formations of alkanes under homogeneous conditions. Chapter 1 offers a comprehensive summary of the main discoveries realized so far. Chapter 2 reviews the so-called electrophilic activation, initiated by Shulpín in the late 60s, and the base for the Catalytica system.  Chapter 3 examines the catalytic borylation of alkanes, discovered by Hartwig, whereas chapter 4 provides an updated vision of the alkane dehydrogenation reaction. Chapter 5 covers the oxygenation of C-H bonds, a field of enormous interest with bioinorganic im-plications, and finally chapter 6 presents the functionalization of alkane C-H bonds by carbene or nitrene insertion. The history of C-H bond activation, and the current research described in this book, highlight the current research and present the reader with an outlook of this field which continues to be explored by an increasingly visionary and enthusiastic group of organic, organometallic, biological and physical chemists.
650 0 _aChemistry.
650 0 _aChemistry, Organic.
650 0 _aCatalysis.
650 1 4 _aChemistry.
650 2 4 _aOrganic Chemistry.
650 2 4 _aCatalysis.
710 2 _aSpringerLink (Online service)
773 0 _tSpringer eBooks
776 0 8 _iPrinted edition:
_z9789048136971
830 0 _aCatalysis by Metal Complexes,
_x0920-4652 ;
_v38
856 4 0 _uhttp://dx.doi.org/10.1007/978-90-481-3698-8
912 _aZDB-2-CMS
999 _c104213
_d104213