000 | 03592nam a22004455i 4500 | ||
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001 | 978-4-431-54156-1 | ||
003 | DE-He213 | ||
005 | 20140220083334.0 | ||
007 | cr nn 008mamaa | ||
008 | 120901s2012 ja | s |||| 0|eng d | ||
020 |
_a9784431541561 _9978-4-431-54156-1 |
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024 | 7 |
_a10.1007/978-4-431-54156-1 _2doi |
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050 | 4 | _aQD450-882 | |
072 | 7 |
_aPNR _2bicssc |
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072 | 7 |
_aSCI013050 _2bisacsh |
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082 | 0 | 4 |
_a541 _223 |
100 | 1 |
_aKumagai, Takashi. _eauthor. |
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245 | 1 | 0 |
_aVisualization of Hydrogen-Bond Dynamics _h[electronic resource] : _bWater-Based Model Systems on a Cu(110) Surface / _cby Takashi Kumagai. |
264 | 1 |
_aTokyo : _bSpringer Japan : _bImprint: Springer, _c2012. |
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300 |
_aXIV, 131 p. 92 illus., 19 illus. in color. _bonline resource. |
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336 |
_atext _btxt _2rdacontent |
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337 |
_acomputer _bc _2rdamedia |
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338 |
_aonline resource _bcr _2rdacarrier |
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347 |
_atext file _bPDF _2rda |
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490 | 1 |
_aSpringer Theses, Recognizing Outstanding Ph.D. Research, _x2190-5053 ; _v125 |
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505 | 0 | _aIntroduction -- Principles and Techniques -- Experiments -- Water Monomer: Structure and Diffusion of a Single Water Molecule -- Water Dimer: Direct Observation of Hydrogen-Bond Exchange -- Water Clusters: Formation of One-Dimensional Water Clusters -- Hydroxyl Group: Tunneling Dynamics of Hydrogen Atom -- Hydroxyl Dimer: Non-linear I–V Characteristics in an STM Junction -- Water-Hydroxyl Complexes: Direct Observation of a Symmetric Hydrogen Bond -- One-Dimensional Water-Hydroxyl Chain Complexes: Hydrogen-Atom Relay Reactions in Real Space -- Conclusions. | |
520 | _aThe hydrogen bond represents an important interaction between molecules, and the dynamics of hydrogen bonds in water create an ever-present question associated with the process of chemical and biological reactions. In spite of numerous studies, the process remains poorly understood at the microscopic level because hydrogen-bond dynamics, such as bond rearrangements and hydrogen/proton transfer reactions, are extremely difficult to probe. Those studies have been carried out by means of spectroscopic methods where the signal stems from the ensemble of a system and the hydrogen-bond dynamics were inferred indirectly. This book addresses the direct imaging of hydrogen-bond dynamics within water-based model systems assembled on a metal surface, using a scanning tunneling microscope (STM). The dynamics of individual hydrogen bonds in water clusters, hydroxyl clusters, and water-hydroxyl complexes are investigated in conjunction with density functional theory. In these model systems, quantum dynamics of hydrogen bonds, such as tunneling and zero-point nuclear motion, are observed in real space. Most notably, hydrogen atom relay reactions, which are frequently invoked across many fields of chemistry, are visualized and controlled by STM. This work presents a means of studying hydrogen-bond dynamics at the single-molecule level, providing an important contribution to wide fields beyond surface chemistry. | ||
650 | 0 | _aChemistry. | |
650 | 0 | _aChemistry, Physical organic. | |
650 | 1 | 4 | _aChemistry. |
650 | 2 | 4 | _aPhysical Chemistry. |
650 | 2 | 4 | _aAtomic/Molecular Structure and Spectra. |
710 | 2 | _aSpringerLink (Online service) | |
773 | 0 | _tSpringer eBooks | |
776 | 0 | 8 |
_iPrinted edition: _z9784431541554 |
830 | 0 |
_aSpringer Theses, Recognizing Outstanding Ph.D. Research, _x2190-5053 ; _v125 |
|
856 | 4 | 0 | _uhttp://dx.doi.org/10.1007/978-4-431-54156-1 |
912 | _aZDB-2-CMS | ||
999 |
_c104052 _d104052 |