000			02337nam a22004695i 4500
001			978-3-642-27254-7
003			DE-He213
005			20140220083307.0
007			cr nn 008mamaa
008			120202s2012 gw | s |||| 0|eng d
020			_a9783642272547 _9978-3-642-27254-7
024	7		_a10.1007/978-3-642-27254-7 _2doi
050		4	_aQD146-197
072		7	_aPNK _2bicssc
072		7	_aSCI013030 _2bisacsh
082	0	4	_a546 _223
100	1		_aVogel, Carola S. _eauthor.
245	1	0	_aHigh- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes _h[electronic resource] : _bA Study of Molecular and Electronic Structure / _cby Carola S. Vogel.
264		1	_aBerlin, Heidelberg : _bSpringer Berlin Heidelberg, _c2012.
300			_aXVIII, 132p. 98 illus., 66 illus. in color. _bonline resource.
336			_atext _btxt _2rdacontent
337			_acomputer _bc _2rdamedia
338			_aonline resource _bcr _2rdacarrier
347			_atext file _bPDF _2rda
490	1		_aSpringer Theses
520			_aCarola Vogel’s PhD thesis focuses on the synthesis, and structural and spectroscopic characterization of the first high valent iron nitride complexes. In her interdisciplinary and collaborative research Carola also describes the reactivity studies of a unique iron (V) nitride complex with water. These studies show that quantitative yields of ammonia are given at ambient conditions. High valent iron nitride and oxo species have been proposed as key intermediates in many bio-catalytic transformations, but until now these species have proven exceedingly challenging to isolate and study. Iron complexes in high oxidation states can thus serve as models for iron-containing enzymes to help us understand biological systems or aid our development of more efficient industrial catalysts.
650		0	_aChemistry.
650		0	_aChemistry, inorganic.
650		0	_aCatalysis.
650		0	_aEnzymes.
650	1	4	_aChemistry.
650	2	4	_aInorganic Chemistry.
650	2	4	_aCatalysis.
650	2	4	_aEnzymology.
710	2		_aSpringerLink (Online service)
773	0		_tSpringer eBooks
776	0	8	_iPrinted edition: _z9783642272530
830		0	_aSpringer Theses
856	4	0	_uhttp://dx.doi.org/10.1007/978-3-642-27254-7
912			_aZDB-2-CMS
999			_c102545 _d102545