000			03119nam a22004695i 4500
001			978-3-642-23129-2
003			DE-He213
005			20140220083300.0
007			cr nn 008mamaa
008			111014s2012 gw | s |||| 0|eng d
020			_a9783642231292 _9978-3-642-23129-2
024	7		_a10.1007/978-3-642-23129-2 _2doi
050		4	_aQD95-96
072		7	_aPNFS _2bicssc
072		7	_aSCI078000 _2bisacsh
082	0	4	_a543.2-543.8 _223
100	1		_aSimpson, Matthew J. _eauthor.
245	1	0	_aTwo Studies in Gas-Phase Ion Spectroscopy _h[electronic resource] : _bVacuum-Ultraviolet Negative Photoion Spectroscopy and Ion-Molecule Reaction Kinetics / _cby Matthew J. Simpson.
264		1	_aBerlin, Heidelberg : _bSpringer Berlin Heidelberg, _c2012.
300			_aXIV, 162 p. _bonline resource.
336			_atext _btxt _2rdacontent
337			_acomputer _bc _2rdamedia
338			_aonline resource _bcr _2rdacarrier
347			_atext file _bPDF _2rda
490	1		_aSpringer Theses
505	0		_aIntroduction and background information -- The experiments.-  Vacuum-ultraviolet negative photoion spectroscopy of SF6, CF4 and SF5CF3 -- Vacuum-ultraviolet negative photoion spectroscopy of CF3Cl, CF3Br and CF3I -- Vacuum-ultraviolet negative photoion spectroscopy of SF5Cl -- Vacuum-ultraviolet negative photoion spectroscopy of small polyatomic molecules -- The reactions of CFn+ (n = 1-3) with C2H4, C2H3F, CH2CF2 and C2HF3 -- The reactions of C2F4+ with C2H4, C2H3F, CH2CF2 and C2HF3 -- Reactions of OH-, O-, CF3-, F- and O2- with C2H4, C2H3F, CH2CF2, C2HF3 and C2F4 .
520			_aIn this thesis Matthew Simpson reports two areas of work in gas ion spectroscopy, each investigation in itself worthy of a PhD. The first study uses tunable vacuum-ultraviolet radiation from a synchrotron to identify negative ions from twenty four photoexcited polyatomic molecules in the gas phase. From these experiments, Matthew collects a vast amount of data and summarises and reviews ion-pair formation from polyatomic molecules.  The second study is on selected ion flow tube mass spectrometry. Matthew investigates the reactions of cations and anions with ethene, monofluoroethene, 1,1-difluoroethene and tetrafluoroethene. In this study Matthew tries to explain why certain products are formed preferentially over other products at a microscopic level of understanding. The data recorded in this thesis form the most comprehensive collection of information about anion formation and are the basis of a review and numerous articles in specialist journals.
650		0	_aChemistry.
650		0	_aSpectroscopy.
650		0	_aChemistry, Physical organic.
650	1	4	_aChemistry.
650	2	4	_aSpectroscopy/Spectrometry.
650	2	4	_aSpectroscopy and Microscopy.
650	2	4	_aPhysical Chemistry.
710	2		_aSpringerLink (Online service)
773	0		_tSpringer eBooks
776	0	8	_iPrinted edition: _z9783642231285
830		0	_aSpringer Theses
856	4	0	_uhttp://dx.doi.org/10.1007/978-3-642-23129-2
912			_aZDB-2-CMS
999			_c102129 _d102129